| 翻訳と辞書 |
Lewis acids and bases
Lewis acid is a chemical species that reacts with a Lewis base to form a Lewis adduct. A Lewis base, then, is any species that donates a pair of electrons to a Lewis acid to form a Lewis adduct. For example, OH− and NH3 are Lewis bases, because they can donate a lone pair of electrons. In the adduct, the Lewis acid and base share an electron pair furnished by the Lewis base.〔http://goldbook.iupac.org/L03508.html〕 Usually the terms Lewis acid and Lewis base are defined within the context of a specific chemical reaction. For example, in the reaction of Me3B and NH3 to give Me3BNH3, Me3B acts as a Lewis acid, and NH3 acts as a Lewis base. Me3BNH3 is the Lewis adduct. The terminology refers to the contributions of Gilbert N. Lewis.
==Depicting adducts==
In many cases, the interaction between the Lewis base and Lewis acid in a complex is indicated by an arrow indicating the Lewis base donating electrons toward the Lewis acid using the notation of a dative bond—for example, Me3B←NH3. Some sources indicate the Lewis base with a pair of dots (the explicit electrons being donated), which allows consistent representation of from the base itself to the complex with the acid:
:Me3B + :NH3 → Me3B:NH3
A center dot may also be used: Me3B·NH3, similar to the notation for hydrate coordination in various crystals. In general, however, the donor–acceptor bond is viewed as simply somewhere along a continuum between idealized covalent bonding and ionic bonding.〔
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
■ウィキペディアで「Lewis acids and bases」の詳細全文を読む
スポンサード リンク
| 翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|